Poly[μ2-aqua-aqua(μ3-1H-benzimidazole-5,6-dicarboxylato-κ3N3:O5:O5′)manganese(II)]
نویسندگان
چکیده
منابع مشابه
catena-Poly[[di-μ-aqua-bis[aquacobalt(II)]]-bis(μ3-1H-benzimidazole-5,6-dicarboxylato]
The title compound, [Co(2)(C(9)H(4)N(2)O(4))(2)(H(2)O)(4)](n), is a one-dimensional polymeric complex with bridging 1H-benzimidazole-5,6-dicarboxyl-ate and aqua ligands. The Co(II) cation has an octa-hedral coordination environment provided by an NO(5) donor set. Adjacent polymeric chains extended along the [100] direction are linked by O-H⋯O and N-H⋯O hydrogen bonds, generating a three-dimensi...
متن کاملPoly[μ2-aqua-diaqua(μ8-3-nitrobenzene-1,2-dicarboxylato)(μ6-3-nitrobenzene-1,2-dicarboxylato)tetrasodium]
In the title layered coordination polymer, [Na(4)(C(8)H(3)NO(6))(2)(H(2)O)(3)](n), the doubly deprotonated 3-nitro-benzene-1,2-dicarboxyl-ate ligands exhibit μ(8)- and μ(6)-coordination modes to the sodium ions, generating sheets lying parallel to (001). The coordination environments of the sodium ions are distorted octa-hedral, distorted trigonal-bipyramidal and moncapped trigonal-prismatic. O...
متن کاملDi-μ-acetato-μ-aqua-bis[acetatobis(1H-benzimidazole)cobalt(II)]
In the title compound, [Co(2)(C(2)H(3)O(2))(4)(C(7)H(6)N(2))(4)(H(2)O)], the half-mol-ecule in the asymmetric unit is completed by a crystallographic twofold rotation axis to give the full mol-ecule. The Co(II) ions are approximately octahedrally coordinated with a cis-N(2)O(4) coordination sphere. The compound features intra-molecular O-H⋯O hydrogen bonds between the non-bridging acetate group...
متن کامل1,2-Diphenyl-1H-benzimidazole
In the title mol-ecule, C19H14N2, the benzimidazole unit is close to being planar [maximum deviation = 0.0102 (6) Å] and forms dihedral angles of 55.80 (2) and 40.67 (3)° with the adjacent phenyl rings; the dihedral angle between the phenyl rings is 62.37 (3)°. In the crystal, one C-H⋯N hydrogen bond and three weak C-H⋯π inter-actions involving the fused benzene ring and the imidazole ring are ...
متن کامل1-Benzyl-1H-benzimidazole
In the title mol-ecule, C(14)H(12)N(2), the benzimidazole ring system is essentially planar (r.m.s. deviation = 0.024 Å). The dihedral angle between the imidazole ring and the benzyl ring is 85.77 (4)°. In the crystal, mol-ecules are linked into chains along the a axis by C-H⋯N hydrogen bonds. In addition, the packing is stabilized by C-H⋯π inter-actions involving both six-membered rings.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810011979